0100481903

open access

Accepted Manuscript

Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy

English (英語)

Nature Chemistry

15(6)

794-802

Springer Nature

2023-03-23

2023-09-23

Increasing levels of CO₂ in the atmosphere is a problem that must be urgently resolved if the rise in current global temperatures is to be slowed. Chemically reducing CO₂ into compounds that are useful as energy sources and carbon-based materials could be helpful in this regard. However, for the CO₂ reduction reaction (CO₂RR) to be operational on a global scale, the catalyst system must: use only renewable energy, be built from abundantly available elements and not require high-energy reactants. Although light is an attractive renewable energy source, most existing CO₂RR methods use electricity and many of the catalysts used are based on rare heavy metals. Here we present a transition-metal-free catalyst system that uses an organohydride catalyst based on benzimidazoline for the CO₂RR that can be regenerated using a carbazole photosensitizer and visible light. The system is capable of producing formate with a turnover number exceeding 8,000 and generates no other reduced products (such as H₂ and CO).

Photocatalysis

学術雑誌論文

This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: https://doi.org/10.1038/s41557-023-01157-6